Abstract
In this report the rational design, synthesis and pharmacological properties of an amide-linked cyclic antagonist analogue of the guinea pig myelin basic protein epitope MBP(72-85) are described. Design of the potent cyclic analogue was based on 2D NOESY nuclear magnetic resonance and molecular dynamics studies carried out in the linear antagonist Ala81MBP(72-85). The cyclic antagonist completely prevented the induction of experimental allergic/autoimmune encephalomyelitis when coinjected with linear and cyclic agonist analogues MBP(72-85) and cyclo(2-9)MBP(72-85).
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Animals
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Drug Design*
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Encephalomyelitis, Autoimmune, Experimental / drug therapy*
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Encephalomyelitis, Autoimmune, Experimental / pathology
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Encephalomyelitis, Autoimmune, Experimental / prevention & control
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Epitopes / administration & dosage
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Epitopes / pharmacology
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Guinea Pigs
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Immunization
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Models, Molecular
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Myelin Basic Protein / chemical synthesis
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Myelin Basic Protein / immunology
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Myelin Basic Protein / pharmacology*
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Nuclear Magnetic Resonance, Biomolecular
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Peptide Fragments / chemical synthesis
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Peptide Fragments / immunology
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Peptide Fragments / pharmacology*
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Peptides, Cyclic / chemical synthesis
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Peptides, Cyclic / immunology
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Peptides, Cyclic / pharmacology
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Rats
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Rats, Inbred Lew
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Spinal Cord / drug effects
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Spinal Cord / pathology
Substances
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Epitopes
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Myelin Basic Protein
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Peptide Fragments
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Peptides, Cyclic
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myelin basic protein 72-85