Infrared laser spectroscopy of jet-cooled carbon clusters: the bending dynamics of linear C9

J Chem Phys. 1993 May 1;98(9):6678-83. doi: 10.1063/1.464785.

Abstract

We report improved measurements for the nu 6 antisymmetric stretch fundamental and observation of the (nu 6 + nu 15)-nu 15 and (nu 6 + 2 nu 15)-2 nu 15 hot bands of the linear C9 carbon cluster by direct absorption diode laser spectroscopy of a supersonic carbon cluster beam. Analysis of these bands characterizes C9 as a semirigid molecule with a bending potential similar to that of C5 and further evidences the alternation in degree of rigidity of linear carbon clusters with the g-u symmetry of the HOMO.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Astronomical Phenomena
  • Astronomy
  • Carbon / chemistry*
  • Coriolis Force
  • Lasers
  • Models, Molecular
  • Molecular Structure*
  • Spectrophotometry, Infrared
  • Spectroscopy, Fourier Transform Infrared

Substances

  • Carbon