Cytotoxic alkaloids and a flavan from the bulbs of Crinum asiaticum var. japonicum

Chem Pharm Bull (Tokyo). 2001 Sep;49(9):1217-9. doi: 10.1248/cpb.49.1217.

Abstract

A new pyrrolophenanthridone alkaloid, criasiaticidine A (1), was isolated from the bulbs of Crinum asiaticum var. japonicum, together with pratorimine (2), lycorine (3) and 4'-hydroxy-7-methoxyflavan (4). The structure of the new alkaloid was determined to be 4,5-etheno-9,10-dihydroxy-6-phenanthridone by spectroscopic means. The cytotoxicity of the isolated compounds 1-4 was evaluated in vitro against Meth-A (mouse sarcoma) and Lewis lung carcinoma (mouse lung carcinoma) tumor cell lines. Furthermore, 3 was examined for in vivo antitumor activity with LLC tumor cells.

MeSH terms

  • Alkaloids / chemistry*
  • Alkaloids / pharmacology*
  • Animals
  • Antineoplastic Agents, Phytogenic / chemistry*
  • Antineoplastic Agents, Phytogenic / pharmacology*
  • Chromatography, Liquid
  • Female
  • Indicators and Reagents
  • Japan
  • Magnetic Resonance Spectroscopy
  • Mass Spectrometry
  • Mice
  • Neoplasm Transplantation
  • Neoplasms, Experimental / drug therapy
  • Phenanthrenes / chemistry
  • Phenanthrenes / pharmacology*
  • Plant Roots / chemistry
  • Plants, Medicinal / chemistry*
  • Spectrophotometry, Ultraviolet
  • Tumor Cells, Cultured

Substances

  • Alkaloids
  • Antineoplastic Agents, Phytogenic
  • Indicators and Reagents
  • Phenanthrenes
  • criasiaticidine A