Abstract
[reaction: see text]. LiN(SiMe3)2, Ph3SiNH2, and LiNH2 can be be used as ammonia equivalents for the Pd-catalyzed coupling of aryl halides. Using these amine derivatives, simple anilines, including ortho-substituted ones, as well as di- and triarylamines can be readily prepared.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Amination
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Amines / chemical synthesis*
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Ammonia / chemistry
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Aniline Compounds / chemical synthesis*
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Benzene Derivatives / chemistry
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Catalysis
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Combinatorial Chemistry Techniques
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Halogens / chemistry
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Palladium / chemistry
Substances
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Amines
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Aniline Compounds
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Benzene Derivatives
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Halogens
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Palladium
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Ammonia