Synthesis and evaluation of novel pseudomycin side-chain analogues. Part 3

Bioorg Med Chem Lett. 2001 Dec 3;11(23):3055-9. doi: 10.1016/s0960-894x(01)00627-8.

Abstract

To increase the therapeutic utility of C-18 side-chain bearing pseudomycin analogue 2, we prepared additional analogues and prodrugs of 2 containing further modifications at various positions within its core structure. Each of the newly synthesized derivatives (10-15) exhibited reduced tail vein toxicity relative to the parent compound. Some of the new pseudomycin derivatives (e.g., 14) also showed improved in vivo antifungal activity relative to its corresponding parent compound.

MeSH terms

  • Animals
  • Antifungal Agents / chemistry*
  • Antifungal Agents / pharmacology*
  • Biochemistry / methods
  • Candidiasis / drug therapy
  • Drug Evaluation, Preclinical
  • Mice
  • Microbial Sensitivity Tests
  • Peptides, Cyclic / chemistry*
  • Peptides, Cyclic / pharmacology*
  • Structure-Activity Relationship
  • Toxicity Tests / methods

Substances

  • Antifungal Agents
  • Peptides, Cyclic
  • pseudomycin A