Neutron investigation of the ion dynamics in liquid mercury: evidence for collective excitations

Phys Rev Lett. 2001 Nov 19;87(21):215504. doi: 10.1103/PhysRevLett.87.215504. Epub 2001 Nov 2.

Abstract

The ion dynamics of liquid mercury was investigated by inelastic neutron scattering. By exploiting an optimized high-resolution ( approximately 1 meV) experimental configuration, the dynamic response function was accurately measured. Collective excitations extending up to 0.6 A(-1) were observed with an associated velocity of 2100+/-80 m/s. This value is notably greater than the sound velocity, but it is provided by a simple Bohm-Staver calculation. The latter finding emphasizes those electron-related features in the ion dynamics, which are common to systems as different as polyvalent and alkali metals.