Elucidation of vasoactive intestinal peptide pharmacophore for VPAC(1) receptors in human, rat, and guinea pig

J Pharmacol Exp Ther. 2002 Apr;301(1):37-50. doi: 10.1124/jpet.301.1.37.

Abstract

Vasoactive intestinal peptide (VIP) is a neurotransmitter involved in a number of pathological and physiological processes. VIP is rapidly degraded and simplified stable analogs are needed. VIP's action was extensively studied in rat and guinea pig. However, it is largely unknown whether its pharmacophore in these species resembles human. To address this issue we investigated the VIP pharmacophore for VPAC(1) (the predominant receptor subtype in cancers and widely distributed in normal tissues) by using alanine and D-amino acid scanning. Interaction with rat, guinea pig, and human VPAC(1) was assessed using transfected Chinese hamster ovary (CHO) and PANC1 cells and cells possessing native VPAC(1). Important species differences existed in the VIP pharmacophore. The human VPAC(1) expressed in CHO cells, which were used almost exclusively in previous studies, differed markedly from the native VPAC(1) in T47D cells. The most important amino acids for determining affinity are His(1), Asp(3), Phe(6), Arg(12), Arg(14), and Leu(23). Ser(2), Asp(8), Asn(9), Thr(11), Val(19), Asn(24), Ser(25), Leu(27), and Asn(28) are not essential for high-affinity interaction/activation. [Ala(2,8,9,11,19,24,25,27,28)]VIP, which contained 11 alanines, was synthesized and it was equipotent to VIP at VPAC(1) receptors in all species and was metabolically stable. Our results show in any design of simplified VIP analogs for VPAC(1) it will be important to consider species differences and it is essential to use transfected systems that reflect the native receptor's pharmacophore. Last, with our results a simplified, metabolically stable VIP analog was identified that should be useful as a prototype for design of selective agonists/antagonists that could be useful therapeutically.

Publication types

  • Comparative Study

MeSH terms

  • Alanine / chemistry
  • Amino Acid Sequence
  • Amino Acid Substitution
  • Amylases / metabolism
  • Animals
  • Blotting, Southern
  • CHO Cells
  • Cells, Cultured
  • Cricetinae
  • Guinea Pigs
  • Humans
  • Male
  • Molecular Sequence Data
  • Pancreas / enzymology
  • Pancreas / metabolism
  • Peptides / chemical synthesis
  • Peptides / pharmacology
  • Rats
  • Receptors, Vasoactive Intestinal Peptide / biosynthesis
  • Receptors, Vasoactive Intestinal Peptide / drug effects*
  • Receptors, Vasoactive Intestinal Peptide / genetics
  • Receptors, Vasoactive Intestinal Polypeptide, Type I
  • Reverse Transcriptase Polymerase Chain Reaction
  • Species Specificity
  • Transfection
  • Tumor Cells, Cultured
  • Vasoactive Intestinal Peptide / chemistry*

Substances

  • Peptides
  • Receptors, Vasoactive Intestinal Peptide
  • Receptors, Vasoactive Intestinal Polypeptide, Type I
  • Vasoactive Intestinal Peptide
  • Amylases
  • Alanine