Flexible inner and outer coordination of Zn(II) N-confused porphyrin complex

Hiroyuki Furuta; Tomoya Ishizuka; Atsuhiro Osuka

doi:10.1021/ja017016p

Flexible inner and outer coordination of Zn(II) N-confused porphyrin complex

J Am Chem Soc. 2002 May 22;124(20):5622-3. doi: 10.1021/ja017016p.

Authors

Hiroyuki Furuta¹, Tomoya Ishizuka, Atsuhiro Osuka

Affiliation

¹ Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan.

PMID: 12010019
DOI: 10.1021/ja017016p

Abstract

Tetra- and dinuclear Zn(II) N-confused porphyrin dimers (1, 2) and pyridine-coordinating Zn(II) monomer complex (3) were synthesized, and the ditopic, inner and outer coordination of Zn metal in the dimer complex (1) was demonstrated by X-ray analyses.