Synthesis, structure determination and properties of MIL-53as and MIL-53ht: the first CrIII hybrid inorganic-organic microporous solids: CrIII(OH).(O2C-C6H4-CO2).(HO2C-C6H4-CO2H)x

Chem Commun (Camb). 2002 Apr 21:(8):822-3. doi: 10.1039/b201381a.

Abstract

The first three-dimensional chromium(III) dicarboxylate compounds have been isolated and their structures solved from powder X-ray diffraction data; the flexible framework of these materials delimits large pores.

MeSH terms

  • Chromium / chemistry*
  • Chromium Compounds / chemical synthesis*
  • Chromium Compounds / chemistry
  • Dicarboxylic Acids / chemistry*
  • Hot Temperature
  • Molecular Conformation
  • X-Ray Diffraction

Substances

  • Chromium Compounds
  • Dicarboxylic Acids
  • Chromium