One-pot synthesis of 1-exo-alkylidene-2,3-anhydro furanoses: convenient precursors for exo-glycals and functionalized C-glycals

Chem Commun (Camb). 2002 Sep 21:(18):2022-3. doi: 10.1039/b205120f.

Abstract

1-exo-Methylene-2,3-anhydro furanoses, obtained from C-glycals in a one-pot, three step operation can be readily transformed into functionalized C-glycals by palladium-catalyzed nucleophilic addition.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbohydrates / chemical synthesis*
  • Furans / chemical synthesis*
  • Glycosides / chemical synthesis

Substances

  • Carbohydrates
  • Furans
  • Glycosides