A general method for convergent synthesis of functionalized exo-glycals based on halogenation and Suzuki cross-coupling of 1-exo-methylene sugars

Chem Commun (Camb). 2002 Sep 21:(18):2024-5. doi: 10.1039/b205121d.

Abstract

Functionalized exo-glycals can be readily obtained by palladium catalyzed Suzuki cross-coupling of halo-exo-glycals with boronic acids.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbohydrates / chemical synthesis*
  • Glycosides / chemistry
  • Hydrocarbons, Brominated / chemical synthesis*
  • Stereoisomerism

Substances

  • Carbohydrates
  • Glycosides
  • Hydrocarbons, Brominated