Modified high-performance liquid chromatographic method for the determination of ertapenem in human urine: enhanced selectivity and automation

J Chromatogr B Analyt Technol Biomed Life Sci. 2002 Nov 5;779(2):341-6. doi: 10.1016/s1570-0232(02)00377-x.

Abstract

A column-switching, reversed-phase high-performance liquid chromatographic (HPLC) assay for a new structurally unique carbapenem antibiotic, ertapenem, in urine has been improved for selectivity and automated using a Packard MultiPROBE II EX pipetting station. The method uses column-switching for on-line extraction of the urine sample. The extraction column, analytical column, mobile phase, and timing of the column-switching valve have been changed to enhance selectivity for the analyte over endogenous background material. Sample transfer and dilution prior to direct-injection into the HPLC system have been accomplished using a Packard MultiPROBE II EX robotic liquid handling system.

MeSH terms

  • Anti-Bacterial Agents / urine*
  • Automation
  • Calibration
  • Chromatography, High Pressure Liquid / methods*
  • Ertapenem
  • Humans
  • Lactams*
  • Linear Models
  • Reproducibility of Results
  • Sensitivity and Specificity
  • Spectrophotometry, Ultraviolet
  • beta-Lactams

Substances

  • Anti-Bacterial Agents
  • Lactams
  • beta-Lactams
  • Ertapenem