Increased protein stability as a mechanism that enhances Nrf2-mediated transcriptional activation of the antioxidant response element. Degradation of Nrf2 by the 26 S proteasome

J Biol Chem. 2003 Feb 14;278(7):4536-41. doi: 10.1074/jbc.M207293200. Epub 2002 Nov 22.

Abstract

Nrf2 (NF-E2-related factor 2) is a central transcription factor involved in the transcriptional activation of many genes encoding phase II drug-metabolizing enzymes via the antioxidant response element. Nrf2 has previously been found to undergo nuclear translocation by a phosphorylation-dependent mechanism mediated by protein kinase C in HepG2 cells treated with tert-butylhydroquinone, beta-naphthoflavone, or 12-O-tetradecanoylphorbol-13-acetate. In the present report, we have found that the levels of Nrf2 were increased in cells treated with tert-butylhydroquinone or beta-naphthoflavone by a post-transcriptional mechanism. Treatment of HepG2 cells with cycloheximide resulted in the loss of Nrf2 within 30 min. By contrast, treatment with the proteasome inhibitors (lactacystin or MG-132) caused an accumulation of Nrf2 as well as an induction of reporter gene activity in cells transfected with the GSTA2 antioxidant response element-chloramphenicol acetyl transferase construct. Similarly, the protein phosphatase inhibitor okadaic acid also caused an accumulation of Nrf2, whereas the reverse effects were observed with PD 98059 and U 0126, two compounds that block the activation of the MAPK/ERK signaling cascade. These data suggest that Nrf2 is degraded by the ubiquitin-dependent pathway and that phosphorylation of Nrf2 leads to an increase in its stability and subsequent transactivation activity.

MeSH terms

  • Antioxidants / pharmacology
  • Butadienes / pharmacology
  • Cell Line
  • DNA-Binding Proteins / chemistry
  • DNA-Binding Proteins / genetics*
  • DNA-Binding Proteins / metabolism*
  • Enzyme Inhibitors / pharmacology
  • Flavonoids / pharmacology
  • Humans
  • Hydroquinones / pharmacology
  • Leucine Zippers
  • NF-E2-Related Factor 2
  • Nitriles / pharmacology
  • Oxidative Stress / genetics
  • Peptide Hydrolases / metabolism*
  • Phosphorylation
  • Proteasome Endopeptidase Complex*
  • Protein Subunits / genetics
  • Protein Subunits / metabolism
  • RNA Processing, Post-Transcriptional / drug effects
  • Trans-Activators / chemistry
  • Trans-Activators / genetics*
  • Trans-Activators / metabolism*
  • Transcriptional Activation / drug effects
  • beta-Naphthoflavone / pharmacology

Substances

  • Antioxidants
  • Butadienes
  • DNA-Binding Proteins
  • Enzyme Inhibitors
  • Flavonoids
  • Hydroquinones
  • NF-E2-Related Factor 2
  • NFE2L2 protein, human
  • Nitriles
  • Protein Subunits
  • Trans-Activators
  • U 0126
  • beta-Naphthoflavone
  • 2-tert-butylhydroquinone
  • Peptide Hydrolases
  • Proteasome Endopeptidase Complex
  • ATP dependent 26S protease
  • 2-(2-amino-3-methoxyphenyl)-4H-1-benzopyran-4-one