South African industry is coming under increasing pressure to reduce the amount of freshwater it uses and the amount of effluent it produces. Water pinch is a cleaner production technique aimed at reducing the freshwater consumption and effluent production within a chemical complex. The design of water-reuse or water pinch networks as applied to the case study of a chlor-alkali complex is considered. Insights are provided into the analysis and formulation of problems for large-scale industrial systems and the application of present techniques and tools to the formulated problem is illustrated. The features of the problem posed by the chlor-alkali facility are discussed and the limitations of the present theory in dealing with this problem highlighted. The concepts of utility-waterpinch analysis and process-water pinch analysis are introduced.