Exposure efficiency, the fraction of material released from a source that is eventually inhaled or ingested, is arguably the simplest of all possible descriptions of the link between pollutant emissions and population exposures. This paper, prepared in late 1999 for the SGOMSEC Workshop, notes that several groups of researchers independently developed the concept of exposure efficiency in the late 1980s and early 1990s but argues that the potential importance of exposure efficiency in risk analysis and life cycle assessment has only recently been appreciated. The paper reviews the history of the concept; discusses and summarizes previous estimates of exposure efficiency for particulate matter and other air pollutants; presents new values for fine particulate matter emitted from power plants and mobile sources in the United States; and illustrates how preliminary estimates of exposure efficiency might be developed. The authors assert that in order for the concept of exposure efficiency to achieve its full potential exposure efficiency estimates for a wide variety of pollutants and sources must be developed and that both the results and methods must be made widely available and accessible to the community of risk assessors and life cycle analysts.