Spironolactone and its main metabolite, canrenoic acid, block human ether-a-go-go-related gene channels

Circulation. 2003 Feb 18;107(6):889-95. doi: 10.1161/01.cir.0000048189.58449.f7.

Abstract

Background: It has been demonstrated that spironolactone (SP) decreases the QT dispersion in chronic heart failure. In this study, the effects of SP and its metabolite, canrenoic acid (CA), on human ether-a-go-go-related gene (HERG) currents were analyzed.

Methods and results: HERG currents elicited in stably transfected Chinese hamster ovary cells were measured with the whole-cell patch-clamp technique. SP decreased HERG currents in a concentration-dependent manner (IC50=23.0+/-1.5 micromol/L) and shifted the midpoint of the activation curve to more negative potentials (Vh=-13.1+/-3.4 versus -18.9+/-3.6 mV, P<0.05) without modifying the activation and deactivation kinetics. SP-induced block (1 micromol/L) appeared at the range of membrane potentials coinciding with that of channel activation, and thereafter, it remained constant, reaching 24.7+/-3.8% at +60 mV (n=6, P<0.05). CA (0.01 nmol/L to 500 micromol/L) blocked HERG channels in a voltage- and frequency-independent manner. CA at 1 nmol/L shifted the midpoint of the activation curve to -19.9+/-1.8 mV and accelerated the time course of channel activation (tau=1064+/-125 versus 820+/-93 ms, n=11, P<0.01). The envelope of the tail test demonstrated that at the very beginning of the pulses to +40 mV (25 ms), a certain amount of block was apparent (31.3+/-9.9%). CA did not modify the voltage-dependence of HERG channel inactivation (Vh=-60.8+/-5.6 versus -62.9+/-3.1 mV, n=6, P>0.05) or the kinetics of the reactivation process at any potential tested. CA and aldosterone also blocked the native I(Kr) in guinea-pig ventricular myocytes.

Conclusions: At concentrations reached after administration of therapeutic doses of SP, CA blocked the HERG channels by binding to both the closed and open states of the channel.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aldosterone / pharmacology
  • Animals
  • CHO Cells / drug effects
  • CHO Cells / metabolism
  • Canrenoic Acid / pharmacology*
  • Cation Transport Proteins*
  • Cricetinae
  • DNA-Binding Proteins*
  • Dose-Response Relationship, Drug
  • ERG1 Potassium Channel
  • Electric Stimulation
  • Ether-A-Go-Go Potassium Channels
  • Guinea Pigs
  • Humans
  • Membrane Potentials / drug effects
  • Membrane Potentials / physiology
  • Myocytes, Cardiac / cytology
  • Myocytes, Cardiac / drug effects
  • Myocytes, Cardiac / metabolism
  • Patch-Clamp Techniques
  • Potassium Channels / drug effects*
  • Potassium Channels / metabolism
  • Potassium Channels, Voltage-Gated*
  • Spironolactone / metabolism
  • Spironolactone / pharmacology*
  • Trans-Activators*
  • Transcriptional Regulator ERG
  • Transfection

Substances

  • Cation Transport Proteins
  • DNA-Binding Proteins
  • ERG protein, human
  • ERG1 Potassium Channel
  • Ether-A-Go-Go Potassium Channels
  • KCNH2 protein, human
  • KCNH6 protein, human
  • Potassium Channels
  • Potassium Channels, Voltage-Gated
  • Trans-Activators
  • Transcriptional Regulator ERG
  • Spironolactone
  • Aldosterone
  • Canrenoic Acid