Light induced excited high spin-state trapping in [FeL2](BF4)2 (L = 2,6-di(pyrazol-1-yl)pyridine)

Victoria A Money; Ivana Radosavljevic Evans; Malcolm A Halcrow; Andrés E Goeta; Judith A K Howard

doi:10.1039/b210146g

Light induced excited high spin-state trapping in [FeL2](BF4)2 (L = 2,6-di(pyrazol-1-yl)pyridine)

Chem Commun (Camb). 2003 Jan 7:(1):158-9. doi: 10.1039/b210146g.

Authors

Victoria A Money¹, Ivana Radosavljevic Evans, Malcolm A Halcrow, Andrés E Goeta, Judith A K Howard

Affiliation

¹ Chemistry Department, Durham University, South Road, Durham, UK DH1 3LE.

PMID: 12611014
DOI: 10.1039/b210146g

Abstract

The spin-crossover complex [FeL2](BF4)2 undergoes a LIESST transition at 30 K on irradiation; the structures of the low-spin ground and high-spin metastable states at this temperature are presented.