Multi-pumping flow system for the spectrophotometric determination of dipyrone in pharmaceutical preparations

J Pharm Biomed Anal. 2003 Aug 8;32(4-5):1011-7. doi: 10.1016/s0731-7085(03)00203-6.

Abstract

A novel flow system for the spectrophotometric determination of dipyrone with p-dimethylaminobenzaldehyde exploiting the multi-pumping approach was developed. The proposed methodology utilises several micro-pumps for propelling the involved fluids under improved mixing conditions, introducing sample/reagent aliquots and providing commuting facilities. As a consequence the multi-pumping system presents high versatility and manifold simplicity, as well as a straightforward operational control and enhanced analytical capabilities. Linearity of the analytical curve was observed within 10 and 400 mg l(-1) dipyrone (r=0.9997; n=6), results were precise (r.s.d.<0.12%; n=20) and sampling rate was 50 h(-1). Detection limit was estimated as 1 mg l(-1) dipyrone. The method was applied to pharmaceutical preparations and the results were in agreement with those obtained by the reference procedure with relative deviations within -1.7 and +2.2%.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Dipyrone / analysis*
  • Dipyrone / chemistry
  • Dosage Forms
  • Flow Injection Analysis / methods
  • Pharmaceutical Preparations / analysis
  • Pharmaceutical Preparations / chemistry
  • Spectrophotometry / methods
  • Technology, Pharmaceutical / methods*

Substances

  • Dosage Forms
  • Pharmaceutical Preparations
  • Dipyrone