Temperature dependence of electron-to-lattice energy transfer in single-wall carbon nanotube bundles

J Nanosci Nanotechnol. 2003 Feb-Apr;3(1-2):145-9. doi: 10.1166/jnn.2003.163.

Abstract

The electron-phonon coupling strength in single-wall carbon nanotube (SWNT) bundles has been studied directly in the time domain by femtosecond time-resolved photoelectron spectroscopy. We have measured the dependence of H(Te, Tl), the rate of energy transfer between the electronic system and the lattice as a function of electron and lattice temperatures Te and Tl. The experiments are consistent with a T5 dependence of H on the electron and lattice temperatures, respectively. The results can be related to the e-ph mass enhancement parameter lambda. The experimentally obtained value of for lambda/[symbol: see text] D2, where [symbol: see text] D is the Debye temperature, suggests that e-ph scattering times at the Fermi level of SWNT bundles can be exceptionally long, exceeding 1.5 ps at room temperature.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Computer Simulation
  • Crystallography / methods*
  • Electrons*
  • Energy Transfer*
  • Macromolecular Substances
  • Materials Testing / methods
  • Models, Chemical
  • Molecular Conformation
  • Nanotechnology / methods
  • Nanotubes, Carbon / chemistry*
  • Spectrophotometry / methods
  • Temperature*

Substances

  • Macromolecular Substances
  • Nanotubes, Carbon