First synthesis of the antifungal and antibacterial agent cladobotryal

Chem Commun (Camb). 2003 Aug 21:(16):2062-3. doi: 10.1039/b306117e.

Abstract

The antifungal and antibacterial agent cladobotryal (1) was synthesized by a convergent route from lactone 5 and aldehyde 12, a key step in the elaboration of the pyridinone ring being conversion of a t-BuOC(O) group on nitrogen into an i-Pr3SiOC(O) group.

MeSH terms

  • Anti-Infective Agents / chemical synthesis*
  • Anti-Infective Agents / chemistry
  • Antifungal Agents / chemical synthesis*
  • Antifungal Agents / chemistry
  • Furans / chemical synthesis*
  • Furans / chemistry
  • Magnetic Resonance Spectroscopy
  • Molecular Structure
  • Pyridones / chemical synthesis*
  • Pyridones / chemistry

Substances

  • 2-(2-buten-2-yl)-3,7-dihydro-3-formyl-3-methyl-5-phenylfuro(2,3-b)pyridin-4(2H)-one
  • Anti-Infective Agents
  • Antifungal Agents
  • Furans
  • Pyridones