Metabolism of deuterium-labeled jasmonic acid and OPC 8:0 in the potato plant (Solanum tuberosum L.)

Biosci Biotechnol Biochem. 2003 Sep;67(9):1903-7. doi: 10.1271/bbb.67.1903.

Abstract

The metabolism of deuterium-labeled (+/-)-jasmonicacid and 3-oxo-2-[(Z)pent-2'-enyl]-cyclopentan-1- octanoic acid in potato (Solanum tuberosum L.) was examined by using cultures of potato single-node stems. Deuterium-labeled (+/-)-jasmonic acid and 3-oxo-2-[(Z) pent-2'-enyl]cyclopentan-1-octanoic acid, which had been prepared from commercially available methyl (+/-)-jasmonate, were fed to the cultures, and the metabolites were extracted from the plants and analyzed by a liquid chromatography-selected ion monitoring system. The metabolism of deuterium-labeled (+/-)-jasmonic acid and 3-oxo-2-[(Z)-2'-pentenyl]cyclopentan-1-octanoic acid to 5' and 4'-O-glucopyranosyloxyjasmoic acids was strongly suggested.

MeSH terms

  • Acetates / chemistry
  • Acetates / metabolism
  • Caprylates / chemistry
  • Caprylates / metabolism*
  • Chromatography, Liquid / methods
  • Culture Techniques / methods
  • Cyclopentanes / chemistry
  • Cyclopentanes / metabolism*
  • Deuterium
  • Glucosides / chemistry
  • Glucosides / metabolism
  • Glycosylation
  • Isotope Labeling
  • Molecular Structure
  • Oxylipins
  • Plant Stems / metabolism
  • Solanum tuberosum / metabolism*
  • Stereoisomerism

Substances

  • 8-(3-oxo-2-cis-((Z)-2-pentenyl)cyclopentyl)octanoic acid
  • Acetates
  • Caprylates
  • Cyclopentanes
  • Glucosides
  • Oxylipins
  • tuberonic acid glucoside
  • tuberonic acid
  • jasmonic acid
  • Deuterium