Synthesis and analysis of nucleosides bearing pyrrolepolyamide binding to DNA

Nucleosides Nucleotides Nucleic Acids. 2003 May-Aug;22(5-8):1309-11. doi: 10.1081/NCN-120022953.

Abstract

An efficient synthesis of adenosine bearing pyrrolepolyamide 1 was achieved by coupling of 3 with 2. The CD spectra obtained at several [ligand ]/[duplex] ratios allowed verification of the formation complex of the DNA duplex [d(CGCAAATTGGC)/d(GCCAATTTGCG)] with 1.

MeSH terms

  • Circular Dichroism
  • DNA / chemistry*
  • Models, Molecular
  • Nucleic Acid Conformation
  • Nucleic Acid Hybridization
  • Nucleosides / chemical synthesis*
  • Nucleosides / chemistry
  • Nylons
  • Oligodeoxyribonucleotides / chemical synthesis*
  • Oligodeoxyribonucleotides / chemistry
  • Pyrroles

Substances

  • Nucleosides
  • Nylons
  • Oligodeoxyribonucleotides
  • Pyrroles
  • DNA