Cefaclor uptake by the proton-dependent dipeptide transport carrier of human intestinal Caco-2 cells and comparison to cephalexin uptake

Biochim Biophys Acta. 1992 Dec 9;1112(2):167-73. doi: 10.1016/0005-2736(92)90388-3.

Abstract

The human Caco-2 cell line spontaneously differentiates in culture to epithelial cells possessing intestinal enterocytic-like properties. These cells possess a proton-dependent dipeptide transport carrier that mediates the uptake of the cephalosporin antibiotic cephalexin (Dantzig, A.H. and Bergin, L. (1990) Biochim. Biophys. Acta 1027, 211-217). In the present study, the uptake of cefaclor was examined and found to be sodium-independent, proton-dependent, and energy-dependent. The initial rate of D-[3-phenyl-3H]cefaclor uptake was measured over a wide concentration range; uptake was mediated by a single saturable transport carrier with a Km of 7.6 mM and a Vmax of 7.6 nmol/min per mg protein and by a non-saturable component. Uptake was inhibited by dipeptides but not amino acids. The carrier showed a preference for the L-isomer. The effect of the presence of a 5-fold excess of other beta-lactam antibiotics was examined on the initial rates of 1 mM cefaclor and 1 mM cephalexin uptake. Uptake rates were inhibited by the orally absorbed antibiotics, cefadroxil, cefaclor, loracarbef, and cephradine and less so by the parenteral agents tested. The initial uptake rates of both D-[9-14C]cephalexin and D-[3-phenyl-3H]cefaclor were competitively inhibited by cephalexin, cefaclor, and loracarbef with Ki values of 9.2-13.2, 10.7-6.2, and 7.7-6.4 mM, respectively. Taken together, these data suggest that a single proton-dependent dipeptide transport carrier mediates the uptake of these orally absorbed antibiotics into Caco-2 cells, and provide further support for the use of Caco-2 cells as a cellular model for the study of the intestinal proton-dependent dipeptide transporter.

Publication types

  • Comparative Study

MeSH terms

  • 2,4-Dinitrophenol
  • Adenocarcinoma
  • Amino Acids / pharmacology
  • Azides / pharmacology
  • Binding, Competitive
  • Carbonyl Cyanide p-Trifluoromethoxyphenylhydrazone / pharmacology
  • Carrier Proteins / metabolism*
  • Cefaclor / metabolism*
  • Cephalexin / metabolism*
  • Cephalosporins / pharmacology
  • Dinitrophenols / pharmacology
  • Dipeptides / metabolism*
  • Dipeptides / pharmacology
  • Humans
  • Hydrogen-Ion Concentration
  • Intestinal Mucosa / metabolism*
  • Intestinal Neoplasms
  • Intestines / drug effects
  • Kinetics
  • Nigericin / pharmacology
  • Oligomycins / pharmacology
  • Sodium Azide
  • Tumor Cells, Cultured

Substances

  • Amino Acids
  • Azides
  • Carrier Proteins
  • Cephalosporins
  • Dinitrophenols
  • Dipeptides
  • Oligomycins
  • Carbonyl Cyanide p-Trifluoromethoxyphenylhydrazone
  • Cefaclor
  • Sodium Azide
  • Cephalexin
  • 2,4-Dinitrophenol
  • Nigericin