Synthesis and characterization of a binary noble metal nitride

Nat Mater. 2004 May;3(5):294-7. doi: 10.1038/nmat1115. Epub 2004 Apr 25.

Abstract

There has been considerable interest in the synthesis of new nitrides because of their technological and fundamental importance. Although numerous metals react with nitrogen there are no known binary nitrides of the noble metals. We report the discovery and characterization of platinum nitride (PtN), the first binary nitride of the noble metals group. This compound can be formed above 45-50 GPa and temperatures exceeding 2,000 K, and is stable after quenching to room pressure and temperature. It is characterized by a very high Raman-scattering cross-section with easily observed second- and third-order Raman bands. Synchrotron X-ray diffraction shows that the new phase is cubic with a remarkably high bulk modulus of 372(+/-5) GPa.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Computer Simulation
  • Materials Testing
  • Metals / chemical synthesis
  • Metals / chemistry
  • Models, Molecular*
  • Molecular Conformation
  • Nitrogen Compounds / chemical synthesis
  • Nitrogen Compounds / chemistry*
  • Platinum Compounds / chemical synthesis
  • Platinum Compounds / chemistry*
  • Pressure
  • Spectrum Analysis, Raman
  • Surface Properties

Substances

  • Metals
  • Nitrogen Compounds
  • Platinum Compounds