Calmodulin bridging of IQ motifs in myosin-V

FEBS Lett. 2004 Jun 4;567(2-3):166-70. doi: 10.1016/j.febslet.2004.04.053.

Abstract

Ca(2+)-saturated calmodulin binds to double-length IQ lever-arm sequences from murine myosin-V, forming a 1:1 "bridging" complex with very high affinity, (K9d)<10 pM for double motifs, IQ34, IQ45 and IQ56). Such a 1:1 complex involves interaction of one calmodulin (CaM) molecule with two adjacent IQ-motifs, providing a molecular mechanism for the observed Ca(2+)-dependent CaM dissociation from the IQ-region. Structural considerations suggest that formation of the 1:1 complex requires a severe distortion of the lever-arm, potentially regulating functional motility. This would be consistent with a recent report of diverse, irregular shapes of the lever arm of myosin-V induced by the presence of Ca(2+).

MeSH terms

  • Amino Acid Motifs
  • Amino Acid Sequence
  • Animals
  • Apoproteins / chemistry
  • Apoproteins / metabolism
  • Binding, Competitive
  • Calcium / metabolism
  • Calmodulin / chemistry*
  • Calmodulin / metabolism*
  • Drosophila Proteins / chemistry
  • Drosophila Proteins / metabolism
  • Kinetics
  • Mice
  • Molecular Sequence Data
  • Myosin Type V / chemistry*
  • Myosin Type V / metabolism*
  • Peptide Fragments / chemistry
  • Peptide Fragments / metabolism
  • Protein Binding
  • Protein Structure, Tertiary
  • Spectrometry, Fluorescence
  • Titrimetry / methods
  • Tryptophan / chemistry

Substances

  • Apoproteins
  • Calmodulin
  • Drosophila Proteins
  • Peptide Fragments
  • Tryptophan
  • Myosin Type V
  • Calcium