Design and synthesis of a solid-supported FR225659 derivative for its receptor screening

Org Lett. 2004 Jul 8;6(14):2477-80. doi: 10.1021/ol049100q.

Abstract

[structure: see text] We describe the design and synthesis of latex particles attached to an FR225659 derivative to identify its receptor proteins. Two key building blocks were prepared by two-step degradation of FR225659 under basic conditions. The designed ligand showed an acceptable level of biological activity to make it of potential value for use in affinity-supported receptor identification. Affinity purification of FR225659-binding proteins using the latex nanoparticles provided three candidate receptor peptides for the biological activity.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carrier Proteins / metabolism
  • Catalysis
  • Indicators and Reagents
  • Inhibitory Concentration 50
  • Latex / chemical synthesis*
  • Latex / chemistry
  • Molecular Structure
  • Oligopeptides / chemical synthesis*
  • Oligopeptides / chemistry

Substances

  • (4-hydroxy-3-(2-(2-propenyl)-4-quinoline)benzoyl)-(3-chloro-4-hydroxyarginyl)-(3-hydroxy-3-methylprolyl)-dehydrovaline
  • Carrier Proteins
  • Indicators and Reagents
  • Latex
  • Oligopeptides