Dual-action hypoglycemic and hypocholesterolemic agents that inhibit glycogen phosphorylase and lanosterol demethylase

J Lipid Res. 2005 Mar;46(3):547-63. doi: 10.1194/jlr.M400436-JLR200. Epub 2004 Dec 16.

Abstract

Diabetic dyslipidemia requires simultaneous treatment with hypoglycemic agents and lipid-modulating drugs. We recently described glycogen phosphorylase inhibitors that reduce glycogenolysis in cells and lower plasma glucose in ob/ob mice (J. Med. Chem., 41: 2934, 1998). In evaluating the series prototype, CP-320626, in dogs, up to 90% reduction in plasma cholesterol was noted after 2 week treatment. Cholesterol reductions were also noted in ob/ob mice and in rats. In HepG2 cells, CP-320626 acutely and dose-dependently inhibited cholesterolgenesis without affecting fatty acid synthesis. Inhibition occurred together with a dose-dependent increase in the cholesterol precursor, lanosterol, suggesting that cholesterolgenesis inhibition was due to lanosterol 14alpha-demethylase (CYP51) inhibition. In ob/ob mice, acute treatment with CP-320626 resulted in a decrease in hepatic cholesterolgenesis with concomitant lanosterol accumulation, further implicating CYP51 inhibition as the mechanism of cholesterol lowering in these animals. CP-320626 and analogs directly inhibited rhCYP51, and this inhibition was highly correlated with HepG2 cell cholesterolgenesis inhibition (R2 = 0.77). These observations indicate that CP-320626 inhibits cholesterolgenesis via direct inhibition of CYP51, and that this is the mechanism whereby CP-320626 lowers plasma cholesterol in experimental animals. Dual-action glycogenolysis and cholesterolgenesis inhibitors therefore have the potential to favorably affect both the hyperglycemia and the dyslipidemia of type 2 diabetes.

MeSH terms

  • Amides / blood
  • Amides / chemical synthesis
  • Amides / pharmacology*
  • Animals
  • Anticholesteremic Agents / chemical synthesis
  • Anticholesteremic Agents / chemistry
  • Anticholesteremic Agents / pharmacology*
  • Cholesterol / biosynthesis
  • Cytochrome P-450 Enzyme Inhibitors*
  • Cytochrome P-450 Enzyme System / metabolism
  • Dogs
  • Dose-Response Relationship, Drug
  • Enzyme Inhibitors / chemical synthesis
  • Enzyme Inhibitors / chemistry
  • Enzyme Inhibitors / pharmacology*
  • Glycogen Phosphorylase / antagonists & inhibitors*
  • Humans
  • Hypoglycemic Agents / chemical synthesis
  • Hypoglycemic Agents / chemistry
  • Hypoglycemic Agents / pharmacology*
  • Indoles / blood
  • Indoles / chemical synthesis
  • Indoles / pharmacology*
  • Lanosterol / blood
  • Liver / drug effects
  • Liver / enzymology
  • Mice
  • Mice, Inbred C57BL
  • Mice, Obese
  • Oxidoreductases / antagonists & inhibitors*
  • Oxidoreductases / metabolism
  • Rats
  • Rats, Sprague-Dawley
  • Sterol 14-Demethylase
  • Structure-Activity Relationship

Substances

  • Amides
  • Anticholesteremic Agents
  • CYP51A1 protein, human
  • Cytochrome P-450 Enzyme Inhibitors
  • Enzyme Inhibitors
  • Hypoglycemic Agents
  • Indoles
  • Lanosterol
  • Cytochrome P-450 Enzyme System
  • Cholesterol
  • Oxidoreductases
  • Cyp51 protein, mouse
  • Sterol 14-Demethylase
  • Glycogen Phosphorylase
  • CP 320626