A luminescent linear trinuclear magnesium complex assembled from a phosphorus-based tris-hydrazone ligand

Chem Commun (Camb). 2005 Jan 28:(4):459-61. doi: 10.1039/b414353a. Epub 2004 Dec 6.

Abstract

A novel linear trinuclear magnesium complex (P(S)[N(CH3)N=CHC6H4-o-O]3)2Mg3 was prepared by the reaction of P(S)[N(CH3))N=CHC6H4-o-OH]3 with MgCl2 x 6H2O in the presence of triethylamine. The trinuclear magnesium complex is fluorescent in solution as well as in the solid-state.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Hydrazones / chemistry*
  • Ligands
  • Luminescent Agents / chemical synthesis*
  • Luminescent Agents / chemistry
  • Magnesium Chloride / chemistry*
  • Molecular Structure
  • Organometallic Compounds / chemical synthesis*
  • Organometallic Compounds / chemistry
  • Organophosphorus Compounds / chemistry*

Substances

  • Hydrazones
  • Ligands
  • Luminescent Agents
  • Organometallic Compounds
  • Organophosphorus Compounds
  • Magnesium Chloride