Design of novel bioisosteres of beta-diketo acid inhibitors of HIV-1 integrase

Antivir Chem Chemother. 2005;16(1):41-61. doi: 10.1177/095632020501600105.

Abstract

HIV-1 integrase (IN) is an attractive and validated target for the development of novel therapeutics against AIDS. Significant efforts have been devoted to the identification of IN inhibitors using various methods. In this context, through virtual screening of the NCI database and structure-based drug design strategies, we identified several pharmacophoric fragments and incorporated them on various aromatic or heteroaromatic rings. In addition, we designed and synthesized a series of 5-aryl(heteroaryl)-isoxazole-3-carboxylic acids as biological isosteric analogues of beta-diketo acid containing inhibitors of HIV-1 IN and their derivatives. Further computational docking studies were performed to investigate the mode of interactions of the most active ligands with the IN active site. Results suggested that some of the tested compounds could be considered as lead compounds and suitable for further optimization.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acquired Immunodeficiency Syndrome / drug therapy
  • Anti-HIV Agents / chemical synthesis
  • Anti-HIV Agents / chemistry
  • Anti-HIV Agents / pharmacology*
  • HIV Integrase / chemistry
  • HIV Integrase / drug effects*
  • HIV Integrase Inhibitors / chemical synthesis
  • HIV Integrase Inhibitors / chemistry
  • HIV Integrase Inhibitors / pharmacology*
  • HIV-1 / drug effects*
  • Keto Acids / analysis
  • Keto Acids / chemical synthesis
  • Keto Acids / chemistry
  • Keto Acids / pharmacology
  • Models, Molecular*

Substances

  • Anti-HIV Agents
  • HIV Integrase Inhibitors
  • Keto Acids
  • HIV Integrase