Abstract
A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Hydrogen-Ion Concentration
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Iron / chemistry*
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Nitrogen / chemistry
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Nonheme Iron Proteins / chemistry*
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Oxidation-Reduction
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Solutions / chemistry
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Sulfides / chemistry*
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Water / chemistry
Substances
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Nonheme Iron Proteins
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Solutions
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Sulfides
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Water
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ferryl iron
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Iron
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Nitrogen