Mild and efficient oxidation of alcohols with sodium periodate catalyzed by polystyrene-bound Mn(III)porphyrin

Majid Moghadam; Shahram Tangestaninejad; Valiollah Mirkhani; Iraj Mohammadpoor-Baltork; Hadi Kargar

doi:10.1016/j.bmc.2005.02.012

Mild and efficient oxidation of alcohols with sodium periodate catalyzed by polystyrene-bound Mn(III)porphyrin

Bioorg Med Chem. 2005 Apr 15;13(8):2901-5. doi: 10.1016/j.bmc.2005.02.012.

Authors

Majid Moghadam¹, Shahram Tangestaninejad, Valiollah Mirkhani, Iraj Mohammadpoor-Baltork, Hadi Kargar

Affiliation

¹ Department of Chemistry, Yasouj University, Yasouj 75914-353, Iran. [email protected]

PMID: 15781399
DOI: 10.1016/j.bmc.2005.02.012

Abstract

Mild and efficient oxidation of primary and secondary alcohols with sodium periodate catalyzed by Mn(TPyP), [manganese(III)tetra(4-pyridyl)porphyrin], supported on chloromethylated polystyrene, [Mn(TPyP)-CMP], at room temperature were reported. This catalyst can be reused consecutively four times in the oxidation of 4-chlorobenzyl alcohol in 97% yield without significant loss of its activity.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Alcohols / chemical synthesis
Alcohols / chemistry*
Catalysis
Manganese / chemistry*
Metalloporphyrins / chemistry*
Molecular Structure
Oxidation-Reduction
Periodic Acid / chemistry*
Polystyrenes / chemistry*

Substances

Alcohols
Metalloporphyrins
Polystyrenes
Periodic Acid
Manganese
metaperiodate