DTPA-bisamide-based MR sensor agents for peroxidase imaging

Org Lett. 2005 Apr 28;7(9):1719-22. doi: 10.1021/ol050208v.

Abstract

[reaction: see text] The synthesis and some properties of two novel DTPA-bisamides are reported. These derivatives were designed as enzyme-activated contrast agents (CA) for magnetic resonance imaging. Both derivatives bear tyramido or 5-hydroxytryptamido groups that could be oligomerized in situ in the presence of peroxidase/H(2)O(2) pair resulting in a net increase in longitudinal (R1) relaxivity.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Contrast Media* / chemical synthesis
  • Contrast Media* / chemistry
  • Gadolinium DTPA / chemistry
  • Magnetic Resonance Imaging*
  • Pentetic Acid / analogs & derivatives
  • Pentetic Acid / chemical synthesis*
  • Pentetic Acid / chemistry
  • Peroxidases / metabolism*

Substances

  • Contrast Media
  • Pentetic Acid
  • Peroxidases
  • Gadolinium DTPA