Abstract
A new strategy for the diastereoselective and convergent synthesis of pterocarpans which is able to control the relative stereochemistry of the molecule through allylation of aromatic aldehydes with cyclic allylsiloxanes is described.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Aldehydes / chemistry
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Allyl Compounds / chemistry
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Crystallography, X-Ray
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Models, Molecular
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Molecular Structure
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Pterocarpans / chemical synthesis*
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Pterocarpans / chemistry
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Siloxanes / chemistry
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Stereoisomerism
Substances
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Aldehydes
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Allyl Compounds
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Pterocarpans
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Siloxanes