Reversible and regioselective reaction of La@C82 with cyclopentadiene

Yutaka Maeda; Jun Miyashita; Tadashi Hasegawa; Takatsugu Wakahara; Takahiro Tsuchiya; Tsukasa Nakahodo; Takeshi Akasaka; Naomi Mizorogi; Kaoru Kobayashi; Shigeru Nagase; Tatsuhisa Kato; Noritaka Ban; Hiroshi Nakajima; Yoshihito Watanabe

doi:10.1021/ja053983e

Reversible and regioselective reaction of La@C82 with cyclopentadiene

J Am Chem Soc. 2005 Sep 7;127(35):12190-1. doi: 10.1021/ja053983e.

Authors

Yutaka Maeda¹, Jun Miyashita, Tadashi Hasegawa, Takatsugu Wakahara, Takahiro Tsuchiya, Tsukasa Nakahodo, Takeshi Akasaka, Naomi Mizorogi, Kaoru Kobayashi, Shigeru Nagase, Tatsuhisa Kato, Noritaka Ban, Hiroshi Nakajima, Yoshihito Watanabe

Affiliation

¹ Department of Chemistry, Tokyo Gakugei University, Koganei, Tokyo 184-8501, Japan.

PMID: 16131174
DOI: 10.1021/ja053983e

Abstract

The reversible and regioselective reaction of La@C82 with cyclopentadiene was carried out. The activation and thermodynamic parameter of the retro-reaction was estimated from the Arrhenius plots of the rate constants.