Abstract
A mononuclear nonheme ferric-peroxo complex bearing a macrocyclic tetradentate N4 ligand, [(TMC)Fe(III)-O2]+, was prepared and used in mechanistic studies of aldehyde deformylation; a catalytic aldehyde deformylation by a nonheme iron(II) complex, [Fe(II)(TMC)]2+, and molecular oxygen is reported as well.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Aldehydes / chemistry*
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Catalysis
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Ferric Compounds / chemical synthesis
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Ferric Compounds / chemistry*
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Formates / chemistry
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Oxygen / chemistry
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Porphyrins / chemistry
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Spectrophotometry, Ultraviolet
Substances
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Aldehydes
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Ferric Compounds
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Formates
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Porphyrins
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peroxo(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)iron(III)
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formic acid
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Oxygen