Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer

Jie-Peng Zhang; Yan-Yong Lin; Wei-Xiong Zhang; Xiao-Ming Chen

doi:10.1021/ja054913a

Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer

J Am Chem Soc. 2005 Oct 19;127(41):14162-3. doi: 10.1021/ja054913a.

Authors

Jie-Peng Zhang¹, Yan-Yong Lin, Wei-Xiong Zhang, Xiao-Ming Chen

Affiliation

¹ State Key Laboratory of Photoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P. R. China.

PMID: 16218592
DOI: 10.1021/ja054913a

Abstract

Aside from a temperature-induced structural transformation, a new nanoporous coordination polymer [Ag6Cl(atz)4].OH.6H2O (Hatz = 3-amino-1,2,4,-triazole) comprised of interpenetrated Ag3(atz)2 coordination nets exhibits a single-crystal-to-single-crystal transformation of a 5-fold to 6-fold net interpenetration change triggered by guest desorption/absorption.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Crystallization
Crystallography, X-Ray
Models, Molecular
Nanostructures / chemistry*
Organometallic Compounds / chemistry
Polymers / chemistry*
Porosity
Silver / chemistry
Temperature*

Substances

Organometallic Compounds
Polymers
Silver