New mono- and bis-carbene samarium complexes: synthesis, X-ray crystal structures and reactivity

Chem Commun (Camb). 2005 Nov 7:(41):5178-80. doi: 10.1039/b510327d. Epub 2005 Sep 28.

Abstract

New samarium carbene complexes have been synthesized and characterized by X-ray diffraction analysis; the carbenic nature was assessed by reactivity studies.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Hydrocarbons / chemistry
  • Methane / analogs & derivatives*
  • Methane / chemistry
  • Models, Molecular
  • Molecular Structure
  • Organometallic Compounds* / chemical synthesis
  • Organometallic Compounds* / chemistry
  • Samarium / chemistry*
  • Stereoisomerism

Substances

  • Hydrocarbons
  • Organometallic Compounds
  • carbene
  • Samarium
  • Methane