Promiscuity in the part-phosphorylative Entner-Doudoroff pathway of the archaeon Sulfolobus solfataricus

FEBS Lett. 2005 Dec 19;579(30):6865-9. doi: 10.1016/j.febslet.2005.11.028. Epub 2005 Dec 1.

Abstract

The hyperthermophilic archaeon Sulfolobus solfataricus metabolises glucose and galactose by a 'promiscuous' non-phosphorylative variant of the Entner-Doudoroff pathway, in which a series of enzymes have sufficient substrate promiscuity to permit the metabolism of both sugars. Recently, it has been proposed that the part-phosphorylative Entner-Doudoroff pathway occurs in parallel in S. solfataricus as an alternative route for glucose metabolism. In this report we demonstrate, by in vitro kinetic studies of D-2-keto-3-deoxygluconate (KDG) kinase and KDG aldolase, that the part-phosphorylative pathway in S. solfataricus is also promiscuous for the metabolism of both glucose and galactose.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adenosine Triphosphate / metabolism
  • Aldehyde-Lyases / analysis
  • Aldehyde-Lyases / chemistry
  • Aldehyde-Lyases / genetics
  • Aldehyde-Lyases / isolation & purification
  • Aldehyde-Lyases / metabolism*
  • Archaea / metabolism*
  • Biotransformation
  • Cloning, Molecular
  • Escherichia coli / genetics
  • Galactose / metabolism
  • Genes, Bacterial
  • Genome, Bacterial
  • Glucose / metabolism
  • Kinetics
  • Models, Biological
  • Molecular Weight
  • Peptides / chemistry
  • Peptides / metabolism
  • Phosphorylation
  • Phosphotransferases (Alcohol Group Acceptor) / analysis
  • Phosphotransferases (Alcohol Group Acceptor) / chemistry
  • Phosphotransferases (Alcohol Group Acceptor) / genetics
  • Phosphotransferases (Alcohol Group Acceptor) / metabolism*
  • Recombinant Proteins / chemistry
  • Recombinant Proteins / isolation & purification
  • Recombinant Proteins / metabolism
  • Substrate Specificity
  • Sulfolobus solfataricus / enzymology*
  • Sulfolobus solfataricus / genetics
  • Sulfolobus solfataricus / metabolism*
  • Temperature

Substances

  • Peptides
  • Recombinant Proteins
  • Adenosine Triphosphate
  • Phosphotransferases (Alcohol Group Acceptor)
  • 2-keto-3-deoxygluconokinase
  • Aldehyde-Lyases
  • 2-keto-3-deoxy-D-glucarate aldolase
  • Glucose
  • Galactose