Radiative lifetime of excitons in carbon nanotubes

Nano Lett. 2005 Dec;5(12):2495-9. doi: 10.1021/nl051828s.

Abstract

We calculate the radiative lifetime and energy bandstructure of excitons in semiconducting carbon nanotubes within a tight-binding approach including the electron-hole correlations via the Bethe-Salpeter equation. In the limit of rapid interband thermalization, the radiative decay rate is maximized at intermediate temperatures and decreases at low temperature because the lowest-energy excitons are optically forbidden. The intrinsic phonons cannot scatter excitons between optically active and forbidden bands, so sample-dependent extrinsic effects that break the symmetries can play a central role. We calculate the diameter-dependent energy splittings between singlet and triplet excitons of different symmetries and the resulting dependence of radiative lifetime on temperature and tube diameter.

MeSH terms

  • Computer Simulation
  • Electric Conductivity
  • Electrons
  • Half-Life
  • Models, Chemical*
  • Models, Molecular*
  • Nanotubes, Carbon / chemistry*
  • Particle Size
  • Radiometry
  • Temperature

Substances

  • Nanotubes, Carbon