Spatial and historical variation in sediment phosphorus fractions and mobility in a shallow lake

Water Res. 2006 Jan;40(2):383-91. doi: 10.1016/j.watres.2005.11.013.

Abstract

Temporal and spatial variation in sediment P composition and mobility were investigated in Loch Leven. Little change was observed in total sediment P (surface sediment at 4m depth), in comparison to a previous study (1990), despite significant reduction of external point sources of P. Labile P and residual P have both increased (0.007-0.039 mg PO(4)-P and 0.121-0.420 mg PO(4)-P per gram dry weight of sediment, respectively) since 1990. An analysis of P fractions, along a depth transect, indicated elevated labile P concentrations in shallow water sediment (<12 m overlying water depth). Regression analysis showed that spatial variability in reductant-adsorbed P was significantly related to sediment chlorophyll a concentration (R(2)=0.733, p<0.05). This may be linked to the production of oxygen, by benthic algae, resulting in the maintenance of an oxygenated layer at the sediment surface. Variation in labile P was best explained by overlying water temperature and equilibrium phosphate concentration (EPC0).

Publication types

  • Historical Article
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Environmental Monitoring
  • History, 20th Century
  • Phosphates / analysis
  • Phosphorus / analysis*
  • Phosphorus / history
  • Regression Analysis
  • Scotland
  • Temperature
  • Time Factors
  • Water / chemistry
  • Water Pollutants / analysis*
  • Water Pollutants / history
  • Water Supply

Substances

  • Phosphates
  • Water Pollutants
  • Water
  • Phosphorus