Abstract
The highly enantioselective hydrovinylation of alpha-alkyl vinylarenes was realized by using nickel complexes of chiral spiro phosphoramidite ligands. The method provided a new approach to the construction of chiral all-carbon quaternary centers.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Hydrocarbons, Aromatic / chemical synthesis*
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Hydrocarbons, Aromatic / chemistry
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Organophosphorus Compounds / chemistry
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Stereoisomerism
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Vinyl Compounds / chemical synthesis*
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Vinyl Compounds / chemistry
Substances
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Hydrocarbons, Aromatic
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Organophosphorus Compounds
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Vinyl Compounds
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phosphoramidite