Formation of a new dynamical mode in -uranium observed by inelastic x-ray and neutron scattering

Phys Rev Lett. 2006 Mar 31;96(12):125501. doi: 10.1103/PhysRevLett.96.125501. Epub 2006 Mar 29.

Abstract

Phonon dispersion curves were obtained from inelastic x-ray and neutron scattering measurements on alpha-uranium single crystals at temperatures from 298 to 573 K. Both measurements showed a softening and an abrupt loss of intensity in the longitudinal optic branch along [00zeta] above 450 K. Above the same temperature a new dynamical mode of comparable intensity emerges along the [01zeta] zone boundary with energy near the top of the phonon spectrum. The new mode forms without a structural transition but coincides with an anomaly in the mechanical deformation behavior. We argue that the mode is an intrinsically localized vibration and formed as a result of a strong electron-phonon interaction.