Determination of geniposide in rat urine after oral administration of the traditional Chinese medicinal preparation yin-zhi-ku decoction by high-performance liquid chromatography

J Chromatogr Sci. 2006 Apr;44(4):227-300. doi: 10.1093/chromsci/44.4.227.

Abstract

A high-performance liquid chromatography method with solid-phase extraction is introduced for the determination of geniposide in rat urine after oral administration of yin-zhi-ku decoction. Geniposide and an internal standard (paeoniflorin) are extracted from urine using Strata cartridges. Analysis of the extract is then performed on a reversed-phase C18 column using acetonitrile-water (14:86, v/v) as eluting solvent system. UV detection is set at 238 nm. The calibration curve for geniposide is linear (r = 0.9996) in the concentration range of 2.0-240 microg/mL. Both intra- and interday precision of the geniposide are determined, and their relative standard deviation does not exceed 10%. The validated method is successfully applied to determine geniposide from rat urine after oral administration of yin-zhi-ku decoction.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Administration, Oral
  • Animals
  • Chromatography, High Pressure Liquid / methods*
  • Drugs, Chinese Herbal / administration & dosage*
  • Iridoids / urine*
  • Male
  • Pyrans / urine*
  • Rats
  • Rats, Sprague-Dawley
  • Reference Standards
  • Reproducibility of Results

Substances

  • Drugs, Chinese Herbal
  • Iridoids
  • Pyrans
  • Yin-Zhi-Ku
  • geniposide