Highly stereoselective synthesis of TMS-, alkyl-, or aryl-substituted cis-[3]cumulenols via alpha-alkynylated zirconacyclopentenes

Angew Chem Int Ed Engl. 2006 Jun 19;45(25):4163-7. doi: 10.1002/anie.200600520.
No abstract available

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aldehydes / chemistry
  • Alkynes / chemistry*
  • Butadienes / chemistry*
  • Cyclopentanes / chemistry*
  • Ketones / chemistry
  • Magnetic Resonance Spectroscopy
  • Organometallic Compounds / chemical synthesis*
  • Organometallic Compounds / chemistry
  • Oxidation-Reduction
  • Stereoisomerism
  • Zirconium / chemistry*

Substances

  • Aldehydes
  • Alkynes
  • Butadienes
  • Cyclopentanes
  • Ketones
  • Organometallic Compounds
  • Zirconium