A miniaturized cell-based fluorescence resonance energy transfer assay for insulin-receptor activation

Anal Biochem. 2006 Aug 15;355(2):267-77. doi: 10.1016/j.ab.2006.05.016. Epub 2006 Jun 9.

Abstract

This report describes the development, optimization, and implementation of a miniaturized cell-based assay for the identification of small-molecule insulin mimetics and potentiators. Cell-based assays are attractive formats for compound screening because they present the molecular targets in their cellular environment. A fluorescence resonance energy transfer (FRET) cell-based assay that measures the insulin-dependent colocalization of Akt2 fused with either cyan fluorescent protein or yellow fluorescent protein to the cellular membrane was developed. This ratiometric FRET assay was miniaturized into a robust, yet sensitive 3456-well nanoplate assay with Z' factors of approximately 0.6 despite a very small assay window (less than twofold full activation with insulin). The FRET assay was used for primary screening of a large compound collection for insulin-receptor agonists and potentiators. To prioritize compounds for further development, primary hits were tested in two additional assays, a biochemical time-resolved fluorescence resonance energy transfer assay to measure insulin-receptor phosphorylation and a translocation-based imaging assay. Results from the three assays were combined to yield 11 compounds as potential leads for the development of insulin mimetics or potentiators.

MeSH terms

  • Active Transport, Cell Nucleus / physiology
  • Animals
  • Bacterial Proteins / chemistry
  • Bacterial Proteins / metabolism
  • Biological Assay / methods*
  • CHO Cells
  • Cell Membrane / metabolism*
  • Cricetinae
  • Fluorescence Resonance Energy Transfer / methods*
  • Green Fluorescent Proteins / chemistry
  • Green Fluorescent Proteins / metabolism
  • Insulin / metabolism*
  • Luminescent Proteins / chemistry
  • Luminescent Proteins / metabolism
  • Nanotechnology
  • Phosphorylation
  • Proto-Oncogene Proteins c-akt / chemistry
  • Proto-Oncogene Proteins c-akt / metabolism
  • Receptor, Insulin / analysis
  • Receptor, Insulin / metabolism*
  • Time Factors

Substances

  • Bacterial Proteins
  • Cyan Fluorescent Protein
  • Insulin
  • Luminescent Proteins
  • yellow fluorescent protein, Bacteria
  • Green Fluorescent Proteins
  • Receptor, Insulin
  • Proto-Oncogene Proteins c-akt