Two pressure-induced superconducting anion radical salts exhibiting different spin states at ambient pressure

Reizo Kato; Akiko Tajima; Akiko Nakao; Masafumi Tamura

doi:10.1021/ja063525l

Two pressure-induced superconducting anion radical salts exhibiting different spin states at ambient pressure

J Am Chem Soc. 2006 Aug 9;128(31):10016-7. doi: 10.1021/ja063525l.

Authors

Reizo Kato¹, Akiko Tajima, Akiko Nakao, Masafumi Tamura

Affiliation

¹ RIKEN, JST-CREST, 2-1 Hirosawa, Wako-shi, Saitama 351-0198, Japan. [email protected]

PMID: 16881622
DOI: 10.1021/ja063525l

Abstract

Pressure-induced superconducting behavior was found in two anion radical salts, EtMe3Z[Pd(dmit)2]2 (dmit = 1,3-dithiole-2-thione-4,5-dithiolate, Z = P, As), that are Mott insulators and exhibit different magnetic and structural transitions at ambient pressure.