Determination of tipranavir in human plasma by reverse phase liquid chromatography with UV detection using photodiode array

Ther Drug Monit. 2006 Aug;28(4):512-6. doi: 10.1097/00007691-200608000-00005.

Abstract

Tipranavir has recently received accelerated approval from the FDA. The initial clinical use of tipranavir will be for patients with prior virologic failure with the presence of key HIV-1 protease inhibitor mutations. In Phase III trials patients with greater virologic response also had higher trough tipranavir concentrations (BI product information 2005). In addition, hepatotoxicity was concentration-related with a higher incidence in those patients exceeding a trough plasma concentration of 48.2 microg/mL (80 microM). Therefore, tipranavir may be an HIV-1 protease inhibitor for which therapeutic drug monitoring (TDM) may be helpful in optimizing outcomes. To quantitate tipranavir concentrations in human plasma, a method using reversed phase high performance liquid chromatography (RP-HPLC) was validated. Detection was effected using a photodiode-array detector, scanning at a wavelength of 254 nm. This method allows for detection of tipranavir to a lower limit of quantitation of 0.390 microg/mL with an interday variation in control value ranging from 2.9 to 4.6%. The method is being used in a clinical therapeutic drug monitoring program that is ongoing in our laboratory.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Calibration
  • Chromatography, High Pressure Liquid / instrumentation
  • Chromatography, High Pressure Liquid / methods*
  • Drug Monitoring / methods
  • Drug Stability
  • HIV Protease Inhibitors / blood
  • HIV Protease Inhibitors / therapeutic use
  • Humans
  • Hydrogen-Ion Concentration
  • Pyridines / blood*
  • Pyridines / therapeutic use
  • Pyrones / blood*
  • Pyrones / therapeutic use
  • Reproducibility of Results
  • Spectrophotometry, Ultraviolet / instrumentation
  • Spectrophotometry, Ultraviolet / methods*
  • Sulfonamides
  • Temperature
  • Time Factors

Substances

  • HIV Protease Inhibitors
  • Pyridines
  • Pyrones
  • Sulfonamides
  • tipranavir