Mitogen-activated protein kinases interacting kinases are autoinhibited by a reprogrammed activation segment

EMBO J. 2006 Sep 6;25(17):4020-32. doi: 10.1038/sj.emboj.7601285. Epub 2006 Aug 17.

Abstract

Autoinhibition is a recurring mode of protein kinase regulation and can be based on diverse molecular mechanisms. Here, we show by crystal structure analysis, nuclear magnetic resonance (NMR)-based nucleotide affinity studies and rational mutagenesis that nonphosphorylated mitogen-activated protein (MAP) kinases interacting kinase (Mnk) 1 is autoinhibited by conversion of the activation segment into an autoinhibitory module. In a Mnk1 crystal structure, the activation segment is repositioned via a Mnk-specific sequence insertion at the N-terminal lobe with the following consequences: (i) the peptide substrate binding site is deconstructed, (ii) the interlobal cleft is narrowed, (iii) an essential Lys-Glu pair is disrupted and (iv) the magnesium-binding loop is locked into an ATP-competitive conformation. Consistently, deletion of the Mnk-specific insertion or removal of a conserved phenylalanine side chain, which induces a blockade of the ATP pocket, increase the ATP affinity of Mnk1. Structural rearrangements required for the activation of Mnks are apparent from the cocrystal structure of a Mnk2 D228G -staurosporine complex and can be modeled on the basis of crystal packing interactions. Our data suggest a novel regulatory mechanism specific for the Mnk subfamily.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adenosine Triphosphate / chemistry
  • Amino Acid Sequence
  • Catalytic Domain
  • Crystallography, X-Ray
  • Humans
  • Intracellular Signaling Peptides and Proteins / antagonists & inhibitors
  • Intracellular Signaling Peptides and Proteins / chemistry*
  • Intracellular Signaling Peptides and Proteins / genetics
  • Magnesium / chemistry
  • Models, Molecular*
  • Molecular Sequence Data
  • Mutation
  • Nuclear Magnetic Resonance, Biomolecular
  • Phenylalanine / chemistry
  • Phosphorylation
  • Protein Conformation
  • Protein Serine-Threonine Kinases / antagonists & inhibitors
  • Protein Serine-Threonine Kinases / chemistry*
  • Protein Serine-Threonine Kinases / genetics
  • Staurosporine / chemistry

Substances

  • Intracellular Signaling Peptides and Proteins
  • Phenylalanine
  • Adenosine Triphosphate
  • MKNK1 protein, human
  • MKNK2 protein, human
  • Protein Serine-Threonine Kinases
  • Staurosporine
  • Magnesium

Associated data

  • PDB/2HW6
  • PDB/2HW7