Bionanoconjugation via click chemistry: The creation of functional hybrids of lipases and gold nanoparticles

Bioconjug Chem. 2006 Nov-Dec;17(6):1373-5. doi: 10.1021/bc0601018.

Abstract

A simple and versatile method for the preparation of functional enzyme-gold nanoparticle conjugates using "click" chemistry has been developed. In a copper-catalyzed 1,2,3-triazole cycloaddition, an acetylene-functionalized Thermomyces lanuginosus lipase has been attached to azide-functionalized water-soluble gold nanoparticles under retention of enzymatic activity. The products have been characterized by gel electrophoresis and a fluorometric lipase activity assay. It is estimated that the equivalent of approximately seven fully active lipase molecules are attached to each nanoparticle.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Gold / chemistry*
  • Lipase / chemistry*
  • Lipase / metabolism*
  • Molecular Structure
  • Nanostructures / chemistry*

Substances

  • Gold
  • Lipase