Bioactive bibenzyl derivatives and fluorenones from Dendrobium nobile

J Nat Prod. 2007 Jan;70(1):24-8. doi: 10.1021/np060449r.

Abstract

Bioassay-guided fractionation of the 60% ethanol extract of the stems of Dendrobium nobile using the DPPH assay led to the isolation of two new bibenzyl derivatives, nobilin D (1) and nobilin E (2), and a new fluorenone, nobilone (3), together with seven known compounds (4-10). Their structures were determined on the basis of spectroscopic analyses. Compounds 1, 2, 4, 7, 8, and 10 exhibited significant antioxidant activity higher than or equivalent to vitamin C in the DPPH assay, and compounds 1, 3, 4, and 7-10 displayed higher antioxidant activity than vitamin C in the ORAC assay. Compounds 1, 2, and 10 also exhibited stronger inhibitory effects on NO production than resveratrol.

MeSH terms

  • Antioxidants / chemistry
  • Antioxidants / isolation & purification*
  • Antioxidants / pharmacology
  • Bibenzyls / chemistry
  • Bibenzyls / isolation & purification*
  • Bibenzyls / pharmacology
  • Biphenyl Compounds
  • Dendrobium / chemistry*
  • Drugs, Chinese Herbal / chemistry
  • Drugs, Chinese Herbal / isolation & purification*
  • Drugs, Chinese Herbal / pharmacology
  • Fluorenes / chemistry
  • Fluorenes / isolation & purification*
  • Fluorenes / pharmacology
  • Nitric Oxide / biosynthesis
  • Nitric Oxide / metabolism
  • Picrates / pharmacology
  • Plant Stems / chemistry
  • Plants, Medicinal / chemistry*
  • Resveratrol
  • Sesquiterpenes, Germacrane
  • Stilbenes / pharmacology

Substances

  • Antioxidants
  • Bibenzyls
  • Biphenyl Compounds
  • Drugs, Chinese Herbal
  • Fluorenes
  • Picrates
  • Sesquiterpenes, Germacrane
  • Stilbenes
  • nobilin D
  • nobilin E
  • nobilone
  • Nitric Oxide
  • 1,1-diphenyl-2-picrylhydrazyl
  • Resveratrol